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Electronic shell structures in bare and protected metal nanoclusters

2016

This short review discusses the concept of the electronic shell structure in the context of metal nanoclusters. Electronic shell structure is a natural consequence of quantization of fermionic states in a quantum confinement, where the symmetry of the confining potential creates energetically close-lying sets of states that reflect the symmetry of the potential. It was introduced in cluster physics in early 1980s and initially influenced greatly by the related model of nuclear shell structure from 1950’s. Three application areas are discussed consisting of free gas phase clusters, clusters supported by insulating oxides or oxide thin films, and clusters that are synthesized by wet chemistry…

superatomligand-stabilized nanoclusterNuclear TheoryShell (structure)General Physics and AstronomyNanotechnologynanoclusterengineering.material010402 general chemistry01 natural sciencesNanoclustersMetalQuantization (physics)Physics::Atomic and Molecular Clustersnoble metalta116ta114simple metal010405 organic chemistryChemistrySuperatom0104 chemical sciencesChemical physicsmagic numbersvisual_artvisual_art.visual_art_mediumengineeringNoble metalAdvances in Physics: X
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